Formed by the reaction between diisocyanates and polyols (multihydroxy compounds), polyurethanes are among the most versatile of plastics, ranging from rigid to elastic forms. Their major use is for foams, with properties varying from good flexibility to high rigidity. Thermoplastic polyurethanes that can be extruded as sheet and film of extreme toughness can also be made.
Polyesters of unsaturated acids
Certain esters can be polymerized to resin and are used on a very large scale in glass-fibre-reinforced plastics.
Unsaturated acid (usually maleic acid in the form of its anhydride) is first polymerized to a relatively short polymer chain by Polyurethanes condensation with a dihydric alcohol such as propylene glycol, the chain length being determined by the relative quantities of the two ingredients The resulting condensation polymer is then diluted with a monomer such as styrene and an initiator for addition polymerization added. This mixture is quite stable at room temperature over a long period. Frequently, a silicone compound is added to promote adhesion to glass fibres, and wax to protect the surface from oxygen inhibition of polymerization. Glass-fibre materials are impregnated with the syrup and polymerization is brought about by raising the Polyurethanes temperature. Alternatively, the polymerization can be carried out at room temperature by addition of a polymerization accelerator to the syrup immediately before impregnation. After an induction period, which can be controlled, polymerization takes place, with rapid increase in temperature, to give a glass-fibre-reinforced cross-linked polymer, which is effectively a thermoset type of plastic and very resistant to heat. The properties of the resin are frequently varied by replacing part of the unsaturated maleic anhydride by anhydrides of saturated acids.
Silicon, unlike carbon, does not form double bonds or long silicon chains. It does Polyurethanes, however, form long chains with oxygen such as in siloxanes with hydrocarbon groups attached to the silicon; these result in a wide range of oils, greases, and rubbers.
Produced through a series of reactions involving replacement of certain atoms in the chain, silicon resins, or silicones, can be used for high- and low-pressure lamination, with glass-fibre reinforcement and with mineral or short glass-fibre fillers, or for molding powders. The outstanding characteristic of these products is high dielectric strength (that is, they are good insulators at high voltages) with low dissipation over a wide temperature and Polyurethanes humidity range. Silicones are not distorted by heat up to 400 С. They are also physiologically inert and therefore valuable for prostheses (artificial body parts).
5. INDUSTRIAL PLASTICS:
RIGID AND FLEXIBLE FOAMS
Rigid polyurethane foams in sandwich forms have wide applications as building components. They are also the best insulants known today and so have wide application in refrigeration and in buildings, where they are applied in fitted slab form or are foamed into cavities at the building site. They can also be applied by spraying about six millimetres thickness with each pass of the spray gun. The Polyurethanes ability to spray a foaming mixture through a single nozzle is a great advantage in application.
A very important use of rigid foam is for furniture parts to reproduce wood structures; these can be injection molded. Polyurethane foam can be screwed and nailed with a retention about equal to white pine lumber.
A major advance in the manufacture of sandwich structures is a new method of injection molding, in which a large machine is used to produce moldings up to 1.2 metres square. Moldings of great strength and any desired surface are obtained.
Flexible foams, usually polyurethane Polyurethanes, are made in slab form up to 2.4 metres in width and as much as 1.5metres high; these are then cut to required shapes or sizes or are molded. The molded foams may be hot molded.
This involves filling heated aluminum castings and gives a product having high resistance to compression, as for automobile seats; or they may be cold molded, a process used particularly for semi-flexible foams with high load-bearing properties. Used almost exclusively by the automobile industry for crash pads, armrests, and dashboard covers, the process involves machine mixing the ingredients and pouring Polyurethanes them into aluminum molds lined with vinyl or acrylo-nitrile-butadiene-styrene skins, which become the cover material for the part.
Polystyrene foams are made in a wide range of densities, from expandable beads, either by extrusion through slot-shaped openings to 40 times the original volume to form boards directly or by foaming in steam chests to form large billets. Using small beads in stainless steel molds, cups can be molded with thin sections.
Thin sheet for packaging can also be made by the tube extrusion technique. Though packaging is a major use for forms made in closed Polyurethanes molds, the largest use is for building panels; they can be plastered directly.
Acrylonitrile-butadiene-styrene can be expanded from pellets and is particularly suitable for wood-grain effects and for the production of heavy sections.
Expanded vinyls can be made from plastisols for flooring or textile linings by calendering with a blowing agent and laminating to a fabric base, and by injection molding for insulation and such articles as shoe soles. An improved material is now obtained from cross-linked polyvinyl chloride and competes with polyester in glass reinforced plastic.
6. BASIC PRINCIPLES OF WELDING
A weld can Polyurethanes be defined as a coalescence of metals produced by heating to a suitable temperature with or without the application of pressure, and with or without the use of a filler material.
In fusion welding a heat source generates sufficient heat to create and maintain a molten pool of metal of the required size. The heat may be supplied by electricity or by a gas flame. Electric resistance welding can be considered fusion welding because some molten metal is formed.
Solid-phase processes produce welds without melting the base material and without the addition of a filler metal. Pressure is Polyurethanes always employed, and generally some heat is provided. Frictional heat is developed in ultrasonic and friction joining, and furnace heating is usually employed in diffusion bonding.
The electric arc used in welding is a high-current, low-voltage discharge generally in the range 10-2,000 amperes at 10-50 volts. An arc column is complex but, broadly speaking, consists of a cathode that emits electrons, a gas plasma for current conduction, and an anode region that becomes comparatively hotter than the cathode due to electron bombardment. Therefore, the electrode, if consumable, is made positive and Polyurethanes, if non-consumable, is made negative. A direct current (dc) arc is usually used, but alternating current (ac) arcs can be employed.
Total energy input in all welding processes exceeds that which is required to produce a joint, because not all the heat generated can be effectively utilized. Efficiencies vary from 60 to 90 percent, depending on the process; some special processes deviate widely from this figure. Heat is lost by conduction through the base metal and by radiation to the surroundings.
Most metals, when heated, react with the atmosphere or other nearby metals. These reactions can be extremely detrimental to the Polyurethanes properties of a welded joint. Most metals, for example, rapidly oxidise when molten. A layer of oxide can prevent proper bonding of the metal. Molten-metal droplets coated with oxide become entrapped in the weld and make the joint brittle. Some valuable materials added for specific properties react so quickly on exposure to the air that the metal deposited does not have the same composition as it had initially. These problems have led to the use of fluxes and inert atmospheres.
In fusion welding the flux has a protective role in facilitating a Polyurethanes controlled reaction of the metal and then preventing oxidation by forming a blanket over the molten material. Fluxes can be active and help in the process or inactive and simply protect the surfaces during joining.
Inert atmospheres play a protective role similar to that of fluxes. In gas-shielded metal-arc and gas-shielded tungsten-arc welding an inert gas—usually argon—flows from an tube surrounding the torch in a continuous stream, displacing the air from around the arc. The gas does not chemically react with the metal but simply protects it from contact with the oxygen Polyurethanes in the air.
The metallurgy of metal joining is important to the functional capabilities of the joint. The arc weld illustrates all the basic features of a joint. Three zones result from the passage of a welding arc: (1) the weld metal, or fusion zone, (2) the heat-affected zone, and (3) the unaffected zone. The weld metal is that portion of the joint that has been melted during welding. The heat-affected zone is a region adjacent to the weld metal that has not been welded but has undergone a change in microstructure or mechanical properties due to the Polyurethanes heat of welding. The unaffected material is that which was not heated sufficiently to alter its properties.
Weld-metal composition and the conditions under which it freezes (solidifies) significantly affect the ability of the joint to meet service requirements. In arc welding, the weld metal comprises filler material plus the base metal that has melted. After the arc passes, rapid cooling of the weld metal occurs. A one-pass weld has a cast structure with columnar grains extending from the edge of the molten pool to the centre of the weld. In a multipass weld, this Polyurethanes cast structure maybe modified, depending on the particular metal that is being welded.
The base metal adjacent to the weld, or the heat-affected zone, is subjected to a range of temperature cycles, and its change in structure is directly related to the peak temperature at any given point, the time of exposure, and the cooling rates. The types of base metal are too numerous to discuss here, but they can be grouped in three classes: (1) materials unaffected by welding heat, (2) materials hardened by structural change, (3) materials hardened by precipitation processes.
Welding produces stresses in materials Polyurethanes. These forces are induced by contraction of the weld metal and by expansion and then contraction of the heat-affected zone. The unheated metal imposes a restraint on the above, and as contraction predominates, the weld metal cannot contract freely, and a stress is built up in the joint. This is generally known as residual stress, and for some critical applications must be removed by heat treatment of the whole fabrication. Residual stress is unavoidable in all welded structures, and if it is not controlled bowing or distortion of the weldment will take place.
Arc Polyurethanes welding
Shielded metal-arc welding accounts for the largest total volume of welding today. In this process an electric arc is struck between the metallic electrode and the workpiece. Tiny globules of molten metal are transferred from the metal electrode to the weld joint. Arc welding can be done with either alternating or direct current. A holder or clamping device with an insulated handle is used to conduct the welding current to the electrode. A return circuit to the power source is made by means of a clamp to the workpiece.
Gas-shielded arc welding, in which the arc Polyurethanes is shielded from the air by an inert gas such as argon or helium, has become increasingly important because it can deposit more material at a higher efficiency and can be readily automated. The tungsten electrode version finds its major applications in highly alloyed sheet materials. Either direct or alternating current is used, and filler metal is added either hot or cold into the arc. Consumable electrode gas-metal arc welding with a carbon dioxide shielding gas is widely used for steel welding. Metal transfer is rapid, and the gas protection ensures a tough weld.
Submerged arc Polyurethanes welding is similar to the above except that the gas shield is replaced with a granulated mineral material as a flux.
Weldability of metals
Carbon and low-alloy steels are the most widely used materials in welded construction. Carbon content largely determines the weldability of carbon steels. Low-alloy steels are generally regarded as those having a total alloying content of less than 6 percent. There are many grades of steel available, and their relative weldability varies.
Aluminum and its alloys are also generally weldable. A very thin oxide film on aluminum tends to prevent good metal flow, however, and suitable fluxes Polyurethanes are used for gas welding. Fusion welding is more effective with alternating current when using the gas-tungsten arc process to enable the oxide to be removed by the arc action.
Copper and its alloys are weldable, but the high thermal conductivity of copper makes welding difficult. Metals such as zirconium, niobium, molybdenum, tantalum, and tungsten are usually welded by the gas-tungsten arc process. Nickel is the most compatible material for joining, is weldable to itself, and is extensively used in dissimilar metal welding of steels, stainless steels and copper Polyurethanes alloys.
Gear is a toothed wheel or cylinder used to transmit rotary or reciprocating motion from one part of a machine to another. Two or more gears, transmitting motion from one shaft to another, constitute a gear train. At one time various mechanisms were collectively called gearing. Now, however, gearing is used only to describe systems of wheels or cylinders with meshing (постоянное зацепление) teeth. Gearing is chiefly used to transmit rotating motion, but can, with suitably designed gears and flat-toothed sectors, be employed to transform reciprocating motion into rotating motion, and vice versa Polyurethanes.
The simplest gear is the spur (зубчатая) gear, a wheel with teeth cut across its edge parallel to the axis. Spur gears transmit rotating motion between two shafts or other parts with parallel axes. In simple spur gearing, the driven shaft revolves in the opposite direction to the driving shaft. If rotation in the same direction is desired, an idler gear (паразитная) is placed between the driving gear and the driven gear. The idler revolves in the opposite direction to the driving gear and therefore turns the driven gear in the same direction as the driving gear. In any Polyurethanes form of gearing the speed of the driven shaft depends on the number of teeth in each gear. A gear with 10 teeth driving a gear with 20 teeth will revolve twice as fast as the gear it is driving, and a 20-tooth gear driving a 10-tooth gear will revolve at half the speed. By using a train of several gears, the ratio of driving to driven speed may be varied within wide limits.
Internal, or annular, gears are variations of the spur gear in which the teeth are cut on the inside of a ring or flanged wheel rather than Polyurethanes on the outside. Internal gears usually drive or are driven by a pinion, a small gear with few teeth. A rack, a flat, toothed bar that moves in a straight line, operates like a gear wheel with an infinite radius and can be used to transform the rotation of a pinion to reciprocating motion, or vice versa.
Bevel gears (конические передачи) are employed to transmit rotation between shafts that do not have parallel axes. These gears have cone-shaped bodies and straight teeth. When the angle between the rotating shafts is 90°, the bevel gears used are called mitre Polyurethanes gears.
These gears have teeth that are not parallel to the axis of the shaft but are spiraled around the shaft in the form of a helix. Such gears are suitable for heavy loads because the gear teeth come together at an acute angle rather than at 90° as in spur gearing. Simple helical gearing has the disadvantage of producing a thrust that tends to move the gears along their respective shafts. This thrust can be avoided by using double helical, or herringbone, gears, which have V-shaped teeth composed of half a right-handed helical tooth Polyurethanes and half a left-handed helical tooth. Hypoid gears are helical bevel gears employed when the axes of the two shafts are perpendicular but do not intersect. One of the most common uses of hypoid gearing is to connect the drive shaft and the rear axle in motor cars. Helical gearing used to transmit rotation between shafts that are not parallel is often incorrectly called spiral gearing.
Another variation of helical gearing is provided by the worm gear, also called the screw gear. A worm gear is a long, thin cylinder that has one or more continuous helical teeth Polyurethanes that mesh with a helical gear. Worm gears differ from helical gears in that the teeth of the worm slide across the teeth of the driven gear instead of exerting a direct rolling pressure. Worm gears are used chiefly to transmit rotation, with a large reduction in speed, from one shaft to another at a 90° angle.